You're gonna hear a lot of ideas, like soaking it in the purple pond, putting it in the freezer and a few others. Those ways work ok I guess but the best way I have found to break one down that was built with tube glue is Testors Acryl #50495. You apply it to the joint just like you would liquid glue with a brush. It will cause you to get some smudges if you are really sloppy and keep it away from clear parts, it will frost em over. When done rinse the parts in water and it stops the action. You might have to use your Xacto to open the joint just a little on heavy glued parts and then flow the juice in. Give it a few minutes and start carefully working the part and it will come loose.
I have tried the other ways and to me this works the best and is the fastest. If you have ever built or seen one of those old IMC kits, you know how many tiny parts are there. I pulled down a Lola T-70 Gloo-Bomb and saved every part but a seat.
I will not even try any of the other methods again after finding this stuff. Do what works best for you but if you try this stuff and learn to use it, you will never mess with the other ways again. It also will clean just about any type paint from your brushes and will help you save one. I have not tried this on models built with super glue so I have no idea how it will react with that. For the old tube glue built stuff it works great.